The Gunners manager had never got the better of his Portuguese
counterpart in eight previous meetings, and that figure became nine
courtesy of goals either side of half-time from Cesar Azpilicueta and
Juan Mata.
The result saw the home side fail to reach the quarter-finals of the
competition for the first time since 2002, but they paid the price for
failing to convert pressure, especially in the second half, into
chances.
Wenger made eight changes to the side that started last Saturday's
win over Crystal Palace, with the trio of Laurent Koscielny, Aaron
Ramsey and Santi Cazorla keeping their places.
Meanwhile, Mourinho's unhappiness at having to send a team out barely
48 hours after the last-gasp win over Manchester City was reflected in a
team selection that featured just Gary Cahill from the 11 that walked
out at Stamford Bridge over a day after Arsenal had left the Selhurst
Park pitch.
The host of changes by both managers meant two of the country's top
sides using many players with little game-time under their belts as
October edged towards November, but it was Chelsea who looked the far
more comfortable as the game unfolded.
The west London outfit won a string of early corners as they enjoyed
the best of the possession without troubling Lukasz Fabianski in the
home goal. At the other end, the hosts failed to test Chelsea's
oldest-ever player, 41-year-old Mark Schwarzer making a rare appearance
as Petr Cech was rested.
But Chelsea took the lead on 25 minutes through an unlikely source as
yet again a defence facing the Blues conspired to present them with a
gilt-edged chance to score.
The confusion as Carl Jenkinson failed to decisively deal with a ball
dropping on the edge of his box had shades of the Joe Hart-Matija
Nastasic incident two days earlier, but this time it was Azpilicueta,
racing upfield from defence following a corner, who was on hand to touch
the ball in off the post for his first Chelsea goal since his move from
Marseille in August 2012.
The goalscorer soon allowed fellow Spaniard Nacho Monreal a shooting
chance, but his raking effort following a mistake from the Chelsea
defender flew across Schwarzer's goal and just wide after a slight touch
off Gary Cahill.
But the goal failed to spur Arsenal on into a concerted response,
with Nicklas Bendtner cutting an isolated figure up front, while Chelsea
were quick to snuff out any home attacks. In fact Mata, required to put
in a shift when his side are without the ball by his manager,
personified Chelsea's committed approach.
Ramsey pulled a shot wide seconds before Mesut Ozil replaced the
anonymous Ryo Miyaichi on the hour as Wenger looked for his side to
properly assert themselves. However Mata's brilliant strike shredded the
script marked "comeback", the Spain international taking one touch to
control the ball after it skimmed off Willian's head before rifling an
unstoppable drive past Fabianski from the edge of Arsenal's area.
Olivier Giroud drove a shot at Schwarzer, but another substitute in
Ramires came close to extending Chelsea's lead within seconds, his fine
dribble only thwarted when Koscielny luckily squeezed the ball to safety
after treading on it.
The away side held their hosts at arm's length for the rest of the
match, and ended the evening as comfortable winners to the delight of
the 9,000 fans that had made the short journey across the capital.
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